Chemistry 30

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Chemical Kinetics

Assignment 1: An Introduction to Chemical Kinetics

This worksheet is also available in the following formats:  Word | RTF | PDF

Work should be shown for all calculations.

1.

During the combustion of methane, CH4, shown by the reaction

CH4(g) + O2(g) → CO2(g) + H2O(g)

the concentration of methane was measured at various time intervals and the following results were obtained:

Time

(s)

[CH4]

(mol · L -1)




10

2.40

20

1.20

30

0.80

40

0.60

Calculate the average rate of loss of methane during the 10 to 40 second time period.

2.

Consider the following reaction: N2(g) + 3 H2(g) → 2 NH3(g)

If the rate of decomposition of N2(g) is 0.03 mol ·L-1· s-1, what is the rate of formation of NH3(g)?

3.

Measurements taken during the reaction CO(g) + NO2(g) → CO2(g) + NO(g)

showed a concentration of carbon monoxide of 0.019 mol ·L-1·s-1 at 27 min and of 0.013 mol · L-1· s-1 at 45 min. Calculate the average rate, over this 18 min period, of each of the following:

a. the loss of carbon monoxide, CO

b. the gain of carbon dioxide, CO2

4.

In the following reaction the average rate of loss of carbon monoxide, over a set period, is 0.15 mol · L-1· s-1.

2 CO(g) → CO2(g) + C(s)

Calculate the average rate of production of carbon dioxide, CO2(g), during the same period.

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Credits | Central iSchool | Sask Learning | Saskatchewan Evergreen Curriculum | Updated: 26-Jun-2006