Chemistry 30

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Thermodynamics

Answers to Practice Questions: Hess's Law Equation
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1.

The standard heats of formation of HCl (g) and HBr (g) are -92.0 kJ/mol and -36.4 kJ/mol respectively. Using this information, calculate ΔH for the following reaction:

Cl2 (g) + 2 HBr (g) → 2 HCl (g) + Br2 (g)

 

Solution:

Solve for ΔH using ΔHreaction = ΣΔHproducts - ΣΔHreactants

It is helpful to write ΔHf values directly below the reaction participants, and find the sum of the reaction and product sides of the equation before using that formula:

Cl2
+
2 HBr
→ 
2 HCl
+
Br2
0
+
2 × (-36.4)
2 × (-92.0)
+
0

 
-72.8
-184.0

 

ΔHreaction = ΣΔHproducts - ΣΔHreactant
  (-184.0) - (-72.8)
  -111.2 kJ   Answer

 

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Credits | Central iSchool | Sask Learning | Saskatchewan Evergreen Curriculum | Updated: 15-Jun-2006